Bøger i Polymer Science and Technology serien

This volume is a eoLleetion of manuseripts based on presenta­ tions at a symposium "Polymerie Separation Media" organized for the Seeond Chemieal Congress of the North Ameriean Continent held in Las Vegas, August 24-29, 1980. The symposium was organized to bring together researehers in the expanding field of separations based on polymerie media. A diverse eross-seetion of re.seareh areas were presented, whieh were linked by the aetive separation agent being a polymerie material. I would like to thank the authors for their endeavours and the audienee for their partieipation, espeeially in light of the late change of venue for this meeting. Finally I am indebted to the Division of Polymer Chemistry Ine. of the Ameriean Chemieal Soeiety for their sponsorship. Anthony R. Cooper, Ph.D., FRSC Palo Alto, California July 1981 v CONTENTS DEDICATION TO BAREND H. J. HOFSTEE . . . . . . . . . . . .. . . 1 PART I TRANSPORT IN POLYMERIC MEDIA Some Condiserations Regarding the Hyperfi1teration of Organic Liquids. 7 I. J. Bass and P. Meares Measurement of Transport Interaction in Membranes . . . . . . . . . . . . . . 19 . . . K. S. Spiegier, T. S. Brun and A. Berg Free Vo1ume Estimates in Crysta11ine and Fi11ed Polymers . . .. .............. 21 H. L. Frisch and A. I. Kreituss Diffusion Coefficients of Po1ystyrenes in Porous Gels From Mass Transfer Dispersion in Gel Permeation Chromatography . . . . . . . . . . . . . . . . . . 27 . . . .

The main goal of the meeting was to facilitate and encourage the application of recent developments in the physical and mathematical sciences to the analysis of deterministic and stochastic processes in nuclear engineering. In contrast with the rapid growth (triggered by computer developments) of nonlinear analysis in other branches of the physical sciences, the theoretical analysis of nuclear reactors is still based on linearized models of the neutronics and thermal-hydraulic feedback loop, an approach that ignores some intrinsic nonlinearities of the real system. The subject of noise was added because of the importance of the noise technique in detecting abnormalities associated with perturbations of sufficient amplitude to generate nonlinear processes. Consequently the organizers of the meeting invited a group of leading researchers in the field of noise and nonlinear phenomena in nuclear systems to report on recent advances in their area of research. A selected subgroup of researchers in areas outside the reactor field provided enlightenment on new theoretical developments of immediate relevance to nuclear dynamics theory.

The II international workshop on "Data Analysis in Astronomy" was intended to provide an overview on the state of the art and the trend in data analy­ sis and image processing in the context of their applications in Astronomy. The need for the organization of a second workshop in this subject derived from the steady. growing and development in the field and from the increasing cross-interaction between methods, technology and applications in Astronomy. The book is organized in four main sections: - Data Analysis Methodologies - Data Handling and Systems dedicated to Large Experiments - Parallel Processing - New Developments The topics which have been selected cover some of the main fields in data analysis in Astronomy. Methods that provide a major contribution to the physical interpretation of the data have been considered. Attention has been devoted to the description of the data analysis and handling organization in very large experiments. A review of the current major satellite and ground based experiments has been included. At the end of the book the following 'Panel Discussions' are included: - Data Analysis Trend in Optical and Radio Astronomy - Data Analysis Trend in X and Gamma Astronomy - Problems and Solutions in the Design of Very Large Experiments - Trend on Parallel Processing Algorithms These contributions in a sense summarize the 'live' reaction of the audience to the various topics.

Polymers and polymer based composites have gained increasingly larger applications in medicine and surgery. Presently, most biomaterials applications rely on industrial substances that were initially developed by industry for non-medical purposes. Moreover, polymers have been often used regardless of their peculiar characteristics which can be viceversa and very attractive for some specific applications. In the past years we have assisted to a significative and faster development of polymer science as well as of medicine and surgery. The assistance of computer aided apparatus, the use of always more advanced instruments, the larger interest of the academic and industrial world, bring continuously new contributions to the research on biomedical and parmaceutical use of polymers. The need of a forum where these specific researchs can be presented and discussed, and the success of the 1st Conference on Polymers in Medicine, held in Porto Cervo in 1982, have encouraged the Editors to plana periodical meeting, focused on polymers and composites, to be held every odd year. This book contains papers selected by an International Scientific Committee among those presented at the 2nd International Conference on Polymers in Medicine, Biomedical and Pharmaceutical Applications, held in Capri, Italy, 3-7 June, 1985. In addition to contributed papers, several Authors were invited to present the "state of the art" as well as their personal contibution on specific key arguments. The level of all contributions was high, the participation well qualified, and the meeting interesting and hopefully pleasant.

This volume comprises the proceedings of a NATO Advanced Study Institute held in Geilo, Norway, between 8-19 April 1985. Although the principal support for the meeting was provided by the NATO Committee for Scientific Affairs, a number of additional sponsors also contributed, allowing the assembly of an unusually large number of internationally rec­ ognized speakers. Additional funds were received from: EXXON Research and Engineering Co. IBM (Europe) Institutt for energiteknikk (NorwaY) Institut Lauge-Langevin (France) The Norwegian Research Council for Science and Humanities NORDITA (Denmark) The Norwegian Foreign Office The U. S. Army Research, Development and Standardization Group (Europe) The U. S. National Science Foundation - The Norwegian Council for Science and Letters The organizing committee would like to take this opportunity to thank these contributors for their help in promoting a most exciting rewarding meeting. This Study Institute was the eighth of a series of meetings held in Geilo on subjects related to phase transitions. In contrast to previous meetings which were principally concerned with transitions in ordered systems, this school addressed the problems which arise when structural order is absent. The unifying feature among the subjects discussed at the school and the link to themes of earlier meetings was the concept of scaling.

Interest in preparing new polymers peaked about 1966. Since that time, industrial and government support for the synthesis and study of new polymers has steadily declined. Gone are the good days when government funds supported a great push to attain ulti­ mate thermal stability for organic polymeric materials. Gone are the good days when many chemical companies, encouraged by the obvious potential for rewards, had great interest and provided support for preparing new polymers. We now often hear managers say "we have enough polymers" or "all we need to do is find additional and better ways to use existing polymers. " The latter often in­ cludes the statement, "we can get the new materials that are wanted from polymer alloys or blends. " Interest in preparing new monomers has also waned, even though it is well recognized that monomers with special functionality are greatly needed to fine-tune existing polymers for specific tasks. Shrinkage of interest in new monomer and polymer research has not come about solely as a result of the obvious maturity of the polymers industry. Since uses for polymers continue to grow and there is still room for good concepts to study, lack of market growth and fields of study have probably not significantly contribu­ ted to that shrinkage.

In recent years, the impact of new experimental techniques (e.g., nuclear physics methods, availability of high-intensity light sources) as well as an increasing demand for atomic collision data in other fields of physics (e.g., plasma physics, astrophysics, laser physics, surface physics, etc.) have stimulated a renewed, strong interest in atomic collision research. Due to the explosive development of the various fields, scientists often even have dif­ ficulty in keeping up with their own area of research; as a result, the overlap between different fields tends to remain rather limited. Instead of having access to the full knowledge accumulated in other fields, one uses only the small fraction which at the moment seems to be of immediate importance to one's own area of interest. Clearly, many fruitful and stimulating ideas are lost in this way, causing progress to be made much more slowly than it could be. Atomic col­ lision physics is no exception to this rule. Although it is of basic interest to many other areas, it is mostly regarded merely as a (nonetheless important) tool by which to gain additional information.

This book contains a collection of original research papers which were presented in honor of the Bordon Award recipient, Professor Eric Baer, on the occasion of the 55th Meeting of the American Chemical Society (Atlanta, Georgia, March, 1981). The contributors are present or former colleagues and students who have worked with him in the Department of Macromolecular Science at Case Institute of Technology of Case Western Reserve University. Throughout his work, Eric Baer has attempted to find the relation­ ships of solid state structure and hierarchy to the resultant pro­ perties from which specific functions are derived. Although he has studied many seemingly unrelated subjects, from irreversible de­ formation, mechanics and yield processes in amorphous polymeric solids to structural organization and mechanical function of ten­ don, his unique goal has been to develop models from the real structure that would allow a quantitative description of properties. Today, this area of "microscience" is rapidly expanding as new and sophisticated applications of polymeric materials with multifunc­ tional properties are emerging from our understanding and control of the solid state. The wide-ranging ideas and the original­ ity of Professor Baer's contributions have stimulated many new concepts which are now widely accepted in the field of high polymers. The contributions to this volume represent many of the areas which he has explored.

For there is hope of a tree, If it be cut down, That it will sprout again And that the tender branch Thereof will not cease. Job XIV (7) Mankind has been blessed with a multitude of resources. In the beginning he utilized almost soley replenishable items such as vegetation and animal protein, for both nourishment and shelter. Gradually, such metals as copper and iron were developed and replaced wood as a material of construction. Cement and glass, although more plentiful than other minerals, also replaced the use of growing sub­ stances. Coal and oil became the primary sources of heat and power. Closer to the focus of this book, petroleum products began to replace the vegetable oils, tannin, wool, cotton, leather, silk, rubber, etc. in a host of applications. Surely, it was argued, the new materials did the job better and cheaper. What they didn't say is that soon we would run out of oil. In any case, research on growing natural products, now called renewable resources, slowed, and these industries sought only to maintain their status quo. The 20th Century saw an unprecedented emphasis and dependence on nonrenewable resources as energy sources (petroleum, coal, ura­ nium) and the fabric of technology (drugs, clothing, shelter, tires, computer parts). The predawn of the 21st Century brings a reali­ zation that a cyclic shift back towards the use of renewable re­ sources for technological application is in order.

This book is derived from a Symposium held at the 190th National American Chemical Society Meeting, which was held in the Fall of 1985, in Chicago, and was sponsored by the Division of Polymeric Materials: Science & Engineering.

This book presents the proceedings of the Symposium on Polymer Alloys, sponsored by the American Chemical Society's Division of OrganiC Coatings and Plastics Chemistry held at the 182nd meeting of the American Chemical Society in New York, in August, 1981.

This book contains the collected papers presented at the Inter national Symposium on Polymers in Medicine, Biomedical and Pharma cological Applications, which was held at Porto Cervo, Italy, May 24-28, 1982.

The biological and biomedical applications of polymeric materials have increased greatly in the past few years. Some earlier books and summaries are available by two of this book's Editors (Gebelein & Carraher) and these should be consul ted for additional information. The books are: "Bioactive Polymeric Systems" (Plenum, 1985);

Water-soluble polymers have been attracting increasing atten tion because of their utility in industrial applications of great current concern. This book is based on papers presented at a symposium held by the American Chemical Society, Division of Organic Coatings and Plastics Chemistry, in New York City on 30-31 August 1972.

This book is derived from a Symposium held at the 190th National American Chemical Society Meeting, which was held in the Fall of 1985, in Chicago, and was sponsored by the Division of Polymeric Materials: Science & Engineering.